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Explainer: How and why fires burn

The secret of fire: Prometheus to pyrolysis

By
9:00am, March 14, 2014

On Earth’s surface, gravity gives flames their characteristic shape (right). But in the weak gravity of space, a flame appears as a sphere (left).

NASA

According to Greek mythology, the gods took fire away from people. Then a hero named Prometheus stole it back. As punishment, the gods chained the thief to a rock, where an eagle fed on his liver. Every night, his liver grew back. And each day, the eagle returned. Like other myths, the Prometheus story offered one explanation for the origins of fire. It doesn’t, however, offer clues to why things burn. That’s what science is for.

Some ancient Greeks believed that fire was a basic element of the universe — one that gave rise to other elements, like earth, water and air. (Aether, that stuff the ancients thought stars were made of, was later added to the list of elements by the philosopher Aristotle.)

Now scientists use the word “element” to describe the most basic types of matter. Fire does not qualify.

A fire’s colorful flame results from a chemical reaction known as combustion. During combustion, atoms rearrange themselves irreversibly. In other words, when something burns, there’s no un-burning it.

Fire also is a glowing reminder of the oxygen that pervades our world. Any flame requires three ingredients: oxygen, fuel and heat. Lacking even one, a fire won’t burn. As an ingredient of air, oxygen is usually the easiest to find. (On planets such as Venus and Mars, with atmospheres containing far less oxygen, fires would be hard to start.) Oxygen’s role is to combine with the fuel.

Any number of sources may supply heat. When lighting a match, friction between the match’s head and the surface against which it’s struck releases enough heat to ignite the coated head. In the Avalanche Fire, lightning delivered the heat.

Fuel is what burns. Almost anything can burn, but some fuels have a far higher flash point — the temperature at which they’ll ignite — than others. 

People feel heat as warmth on the skin. Not atoms. The building blocks of all materials, atoms just get antsy as they warm. They initially vibrate. Then, as they warm even more, they start dancing, faster and faster. Apply enough heat, and atoms will break the bonds linking them together.

Wood, for example, contains molecules made from bound atoms of carbon, hydrogen and oxygen (and smaller amounts of other elements). When wood gets hot enough — such as when lightning hits or a log is tossed on an already burning fire — those bonds break. The process, called pyrolysis, releases atoms and energy.

Unbound atoms form a hot gas, mingling with oxygen atoms in the air. This glowing gas — and not the fuel itself — produces the spooky blue light that appears at the base of a flame.

But the atoms don’t stay single long: They quickly bond with oxygen in the air in a process called oxidation. When carbon bonds with oxygen, it produces carbon dioxide — a colorless gas. When hydrogen bonds with oxygen, it produces water vapor — even as the wood burns.

Fires burn only when all that atomic shuffling releases enough energy to keep the oxidation going in a sustained chain reaction. More atoms released from the fuel combine with nearby oxygen. That releases more energy, which releases more atoms. This heats the oxygen — and so on.

The orange and yellow colors in a flame appear when extra, free-floating carbon atoms get hot and begin to glow. (These carbon atoms also make up the thick black soot that forms on grilled burgers or the bottom of a pot heated over a fire.)

Power Words

atom  The basic unit of a chemical element.

bond  (in chemistry) Attractive forces between atoms that are strong enough to make the linked elements function as a single unit. Some of the attractive forces are weak, some are very strong. All bonds appear to link atoms through a sharing of — or an attempt to share — electrons.

carbon  The chemical element having the atomic number 6. It is the physical basis of all life on Earth. Carbon exists freely as graphite and diamond. It is an important part of coal, limestone and petroleum, and is capable of self-bonding, chemically, to form an enormous number of chemically, biologically and commercially important molecules.

chemical reaction  A process that involves rearrangement of the molecules or structure of a substance, as opposed to a change in physical form.

climate  The weather conditions prevailing in an area in general or over a long period.

combust  To consume by fire. Combustion is the process of burning.

element  Each of more than one hundred substances that cannot be broken down into simpler substances.

fire  The burning of some fuel, creating a flame that releases light and heat.

fuel  Any material that will release energy during a controlled chemical or nuclear reaction. Fossil fuels (coal, natural gas and petroleum) represent a common type that liberates its energy through chemical reactions that take place when heated (usually to the point of burning).

molecule  An electrically neutral group of atoms that represents the smallest possible amount of a chemical compound. Molecules can be made of single types of atoms or of different types. For example, the oxygen in the air is made of two oxygen atoms (O2), but water is made of two hydrogen atoms and one oxygen atom (H2O).

oxygen  A gas that makes up about 21 percent of the atmosphere. All animals and many microorganisms need oxygen to fuel their metabolism.

pyrolysis  A chemical change triggered by heat, often due to fire.

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